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废弃沥青材料的循环利用关键技术研究

杨林江

《中国工程科学》 2015年 第17卷 第1期   页码 56-61

摘要：

通过了解国内外沥青路面再生技术的发展现状，剖析沥青路面老化、再生机理，提出了废旧沥青混合料循环利用的技术，研发出一套行之有效的沥青路面热再生技术，以适应当今形势下的沥青路面再生、资源循环利用和环境保护的需要，为建设资源节约型、环境友好型社会而努力。

关键词： 沥青；路面；废旧料；循环利用；热再生技术；再生沥青混合料    

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Green Road Construction Technologies in Guangzhou

Guan-feng An,Wen-yuan Huang,Jing-feng Zhang

《工程管理前沿（英文）》 2016年 第3卷 第1期   页码 80-86 doi: 10.15302/J-FEM-2016002

摘要： Total road pavement in Guangzhou reaches 77 ×10 m . Its huge maintenance and potential rehabilitation calls for a green road system. This paper presents a discussion, first about green road construction technologies together with their applications and development like reclaimed asphalt pavement, rubberized asphalt pavement, and warm mix asphalt; and then, about the key obstacles for promotion and activities, primarily for green road promotion, in the perspectives of the current technical and application situations in China and separately in Guangzhou. Based on environmental and conditional analysis, as well as a development expectation from an industrial viewpoint, this paper creates a development trend of green road technologies.

关键词： road     green construction     recycling of waste asphalt     rubber asphalt    

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Copper fractal growth during recycling from waste printed circuit boards by slurry electrolysis

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1405-7

摘要：

• Copper fractal growth was observed during WPCBs recycling by slurry electrolysis.

关键词： Dendritic copper     Fractal growth     WPCBs     Slurry electrolysis    

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Aging properties and aging mechanism of activated waste rubber powder modified asphalt binder based on

《结构与土木工程前沿（英文）》 2023年 第17卷 第4期   页码 625-636 doi: 10.1007/s11709-023-0938-1

摘要： The research and development of high-performance pavement materials has been intensified owing to the demand for long-life pavements. This study is performed to develop a novel pavement material using waste rubber powder, waste lubricating by-product (LBP), and asphalt. Subsequently, the aging properties and aging mechanism of activated waste rubber powder modified asphalt (ARMA) are investigated based on its rheological properties and micro-characterization. The rheological results show that, compared with waste rubber powder modified asphalt (RMA), ARMA offers a higher aging resistance and a longer fatigue life. A comparison and analysis of the rheological aging parameters of ARMA and RMA show that LBP activation diminishes the aging sensitivity of ARMA. The micro-characterization result shows that the aging of ARMA may be caused by the fact that LBP-activated waste rubber powder is more reactive and can form a dense colloidal structure with asphalt. Therefore, the evaporation loss of asphalt light components by heat and the damage to the colloidal structure by oxygen during the aging process are impeded, and the thermal-oxidative aging resistance of ARMA is improved.

关键词： rubber powder modified asphalt     aging     mechanism     rheological     characterization    

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Recycling Materials from Waste Electrical and Electronic Equipment

Jinhui Li

《环境科学与工程前沿（英文）》 2017年 第11卷 第5期 doi: 10.1007/s11783-017-1001-z

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Multi-Component Resource Recycling from Waste Light-Emitting Diode Under Hydrothermal Condition: Plastic

Yongliang Zhang,Lu Zhan,Zhenming Xu,

《工程（英文）》 doi: 10.1016/j.eng.2023.04.008

摘要： Light emitting diodes (LEDs) have accounted for most of the lighting market as the technology matures and costs continue to reduce. As a new type of e-waste, LED is a double-edged sword, as it contains not only precious and rare metals but also organic packaging materials. In previous studies, LED recycling focused on recovering precious and strategic metals while ignoring harmful substances such as organic packaging materials. Unlike crushing and other traditional methods, hydrothermal treatment can provide an environment-friendly process for decomposing packaging materials. This work developed a closed reaction vessel, where the degradation rate of plastic polyphthalamide (PPA) was close to 100%, with nano-TiO2 encapsulated in plastic PPA being efficiently recovered, while metals contained in LED were also recycled efficiently. Besides, the role of water in plastic PPA degradation that has been overlooked in current studies was explored and speculated in detail in this work. Environmental impact assessment revealed that the proposed recycling route for waste LED could significantly reduce the overall environmental impact compared to the currently published processes. Especially the developed method could reduce more than half the impact of global warming. Furthermore, this research provides a theoretical basis and a promising method for recycling other plastic-packaged e-waste devices, such as integrated circuits.

关键词： Waste LED     Hydrothermal treatment     Recycling     Plastic PPA degradation     Packaging materials    

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Region-gridding recycling of bulk organic waste: Emerging views based on coordinated urban and rural

Wenbing Tan, Dongyu Cui, Xiaohui Zhang, Beidou Xi

《环境科学与工程前沿（英文）》 2020年 第14卷 第6期 doi: 10.1007/s11783-020-1291-4

摘要： Abstract Bulk organic waste (BOW) has a large output in China. The improper disposal of BOW will not only bring serious environmental pollution, but also cause waste of biomass resources. The viewpoint proposes a region-gridding recycling management system of BOW that highlights the coordinated development of environmental, agricultural and energy elements in urban and rural areas. The viewpoint aims to drive the upstream and downstream industrial chains of BOW treatments, avoid the repeated construction of resource facilities, guide the upgrading of resource-based technologies, promote the professionalization of farmers, and thus built the high-quality modern agricultural recycling industrial park based on system management.

关键词： Bulk organic waste     Recycling     Urban-rural coordination     Management system    

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A critical review on the recycling of copper and precious metals from waste printed circuit boards using

Zebing Wu, Wenyi Yuan, Jinhui Li, Xiaoyan Wang, Lili Liu, Jingwei Wang

《环境科学与工程前沿（英文）》 2017年 第11卷 第5期 doi: 10.1007/s11783-017-0995-6

摘要： Currently, increasing amounts of end-of-life (EoL) electronic products are being generated due to their reduced life spans and the unavailability of suitable recycling technologies. In particular, waste printed circuit boards (PCBs) have become of global concern with regard to environmental issues because of their high metal and toxic material contents, which are pollutants. There are many environmental threats owed to the disposal of electronic waste; off-gasses, such as dioxins, furans, polybrominated organic pollutants, and polycyclic aromatic hydrocarbons, can be generated during thermal treatments, which can cause serious health problems if effective off-gas cleaning systems are not developed and improved. Moreover, heavy metals will dissolve, and release into the ground water from the landfill sites. Such waste PCBs contain precious metals which are of monetary value. Therefore, it is beneficial to recover the metal content and protect the environment from pollution. Hydrometallurgy is a successful technique used worldwide for the recovery of precious metals (especially gold and silver) from ores, concentrates, and waste materials. It is generally preferred over other methods because it can offer high recovery rates at a relatively low cost. This article reviews the recent trends and developments with regard to the recycling of precious metals from waste PCBs through hydrometallurgical techniques, such as leaching and recovery.

关键词： Waste PCBs     Precious metals     Hydrometallurgy     Recycling     Leaching     Recovery    

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risks of heavy metals, polybrominated diphenyl ethers, and polychlorinated dibenzo-dioxins/furans at e-wasterecycling sites in South China

《环境科学与工程前沿（英文）》 2023年 第17卷 第7期 doi: 10.1007/s11783-023-1679-z

摘要：

● Heavy metals and organic toxins may persist in legacy sites for a long time.

关键词： E-waste     Human health risk     Organ risk     Heavy metal toxicity     PBDE     PCDD/F    

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Characterization of chlorine and heavy metals for the potential recycling of bottom ash from municipalsolid waste incinerators as cement additives

Boran WU, Dongyang WANG, Xiaoli CHAI, Fumitake TAKAHASHI, Takayuki SHIMAOKA

《环境科学与工程前沿（英文）》 2016年 第10卷 第4期 doi: 10.1007/s11783-016-0847-9

摘要： Industrial waste mixed with MSW is the main source of heavy metal in bottom ash. Chlorine content in bottom ash is controlled both by plastic and kitchen waste. Insoluble chlorine in Chinese MSWI bottom ash exists primarily as AlOCl. Bottom ash is an inevitable by-product from municipal solid waste (MSW) incineration plants. Recycling it as additives for cement production is a promising disposal method. However, the heavy metals and chlorine are the main limiting factors because of the potential environmental risks and corrosion of cement kilns. Therefore, investigating heavy metal and chlorine characteristics of bottom ash is the significant prerequisite of its reuse in cement industries. In this study, a correlative analysis was conducted to evaluate the effect of the MSW components and collection mode on the heavy metal and chlorine characteristics in bottom ash. The chemical speciation of insoluble chlorine was also investigated by synchrotron X-ray diffraction analysis. The results showed that industrial waste was the main source of heavy metals, especially Cr and Pb, in bottom ash. The higher contents of plastics and kitchen waste lead to the higher chlorine level (0.6 wt.%–0.7 wt.%) of the bottom ash. The insoluble chlorine in the MSW incineration bottom ash existed primarily as AlOCl, which was produced under the high temperature (1250℃) in incinerators.

关键词： Bottom ash     Chlorine     Heavy metals     Waste inputs     Synchrotron X-ray diffraction     AlOCl    

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Spent rechargeable lithium batteries in e-waste: composition and its implications

Xianlai ZENG,Jinhui LI

《环境科学与工程前沿（英文）》 2014年 第8卷 第5期   页码 792-796 doi: 10.1007/s11783-014-0705-6

摘要： The amount of spent rechargeable lithium batteries (RLBs) is growing rapidly owing to wide application of these batteries in portable electronic devices and electric vehicles, which obliges that spent RLBs should be handled properly. Identification of spent RLBs can supply fundamental information for spent RLBs recycling. This study aimed to determine the differences of physical components and chemical compositions among various spent RLBs. All the samplings of RLBs were rigorously dismantled and measured by an inductive coupled plasma atomic emission spectrometer. The results indicate that the average of total weight of the separator, the anode and the cathode accounted for over 60% of all the RLBs. The weight ratio of valuable metals ranged from 26% to 76%, and approximately 20% of total weight was Cu and Al. Moreover, no significant differences were found among different manufacturers, applications, and electrolyte types. And regarding portable electronic devices, there is also no significant difference in the Co-Li concentration ratios in the leaching liquid of RLBs.

关键词： rechargeable lithium batteries     e-waste     physical components     difference analysis     recycling    

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Thermal cracking of waste printed wiring boards for mechanical recycling by using residual steam preprocessing

Yao CHEN, Jinhui LI, Huabo DUAN, Zhishi WANG

《环境科学与工程前沿（英文）》 2011年 第5卷 第2期   页码 167-174 doi: 10.1007/s11783-011-0308-4

摘要： Mechanical waste-processing methods, which combine crushing and separation processes for the recovery of valuable materials, have been widely applied in waste printed wiring board (PWB) treatment. However, both the high impact toughness and the tensile and flexural strengths of whole PWB with a laminated structure result in great energy consumption and severe abrasion of the cutters during multi-level crushing. In addition, the high temperatures occurring in continual crushing probably cause the decomposition of the polymer matrix. A thermal-crack method using residual steam as the heating medium has been developed to pre-treat waste PWBs. This treatment reduces the mechanical strength in order to improve the recovery rate of valuable materials in subsequent mechanical recycling. The changes of the PWBs’ macro-mechanical properties were studied to evaluate thermal expansion impacts associated with changes in temperature, and the dynamic dislocation micro-structures were observed to identify the fracture mechanism. The results showed that thermal cracking with steam at the temperature of 500 K can effectively attenuate the mechanical properties of waste PWBs, by reducing the impact, tensile and flexural strengths respectively, by 59.2%, 49.3% and 51.4%, compared to untreated PWB. Thermal expansion can also facilitate the separation of copper from glass fiber by reducing peel resistance by 95.4% at 500 K. It was revealed that the flexural fracture was a transverse cracking caused by concentrated stress when the heating temperature was less than 500 K, and shifted to a vertical cracking after exceeding 500 K.

关键词： waste printed wiring board (PWB)     residue steam     thermal-crack     mechanical properties    

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Recycling polymeric waste from electronic and automotive sectors into value added products

Abhishek Kumar, Veena Choudhary, Rita Khanna, Romina Cayumil, Muhammad Ikram-ul-Haq, Veena Sahajwalla, Shiva Kumar I. Angadi, Ganapathy E. Paruthy, Partha S. Mukherjee, Miles Park

《环境科学与工程前沿（英文）》 2017年 第11卷 第5期 doi: 10.1007/s11783-017-0991-x

摘要： The environmentally sustainable disposal and recycling of ever increasing volumes of electronic waste has become global waste management issue. The addition of up to 25% polymeric waste PCBs (printed circuit boards) as fillers in polypropylene (PP) composites was partially successful: while the tensile modulus, flexural strength and flexural modulus of composites were enhanced, the tensile and impact strengths were found to decrease. As a lowering of impact strength can significantly limit the application of PP based composites, it is necessary to incorporate impact modifying polymers such as rubbery particles in the mix. We report on a novel investigation on the simultaneous utilization of electronic and automotive rubber waste as fillers in PP composites. These composites were prepared by using 25 wt.% polymeric PCB powder, up to 9% of ethylene propylene rubber (EPR), and PP: balance. The influence of EPR on the structural, thermal, mechanical and rheological properties of PP/PCB/EPR composites was investigated. While the addition of EPR caused the nucleation of the β crystalline phase of PP, the onset temperature for thermal degradation was found to decrease by 8%. The tensile modulus and strength decreased by 16% and 19%, respectively; and the elongation at break increased by ~71%. The impact strength showed a maximum increase of ~18% at 7 wt.%–9 wt.% EPR content. Various rheological properties were found to be well within the range of processing limits. This novel eco-friendly approach could help utilize significant amounts of polymeric electronic and automotive waste for fabricating valuable polymer composites.

关键词： E-waste     Polymer composites     Recycling     Rubber     Waste PCBs     Filler    

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Toward separation at source: Evolution of Municipal Solid Waste management in China

Jianguo Liu, Shuyao Yu, Yixuan Shang

《环境科学与工程前沿（英文）》 2020年 第14卷 第2期 doi: 10.1007/s11783-020-1232-2

摘要： Municipal Solid Waste (MSW) management in China has been transitioning from a mixed collection and treatment system to a separated collection and treatment system. The continuous rise of MSW treatment capacity and the optimization of technology structure provided basic facility support for China to promote MSW separation at source. China preferred a four-type separation system. Regulated recycling should be enhanced to improve the efficiency and sustainability of recycling industry. As food waste is the main composition of MSW in China, 20%–30% of the food waste diversion and land application could maximize the comprehensive environmental performance. Incineration is to be the pillar technology in MSW separated treatment system in China.

关键词： Municipal Solid Waste     Separation at source     Recycling     Biological treatment     Incineration    

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Carbon footprint assessment for the waste management sector: A comparative analysis of China and Japan

Lu SUN, Zhaoling LI, Minoru FUJII, Yasuaki HIJIOKA, Tsuyoshi FUJITA

《能源前沿（英文）》 2018年 第12卷 第3期   页码 400-410 doi: 10.1007/s11708-018-0565-z

摘要：

Waste management is becoming a crucial issue in modern society owing to rapid urbanization and the increasing generation of municipal solid waste (MSW). This paper evaluates the carbon footprint of the waste management sector to identify direct and indirect carbon emissions, waste recycling carbon emission using a hybrid life cycle assessment and input-output analysis. China and Japan was selected as case study areas to highlight the effects of different industries on waste management. The results show that the life cycle carbon footprints for waste treatment are 59.01 million tons in China and 7.01 million tons in Japan. The gap between these footprints is caused by the different waste management systems and treatment processes used in the two countries. For indirect carbon footprints, China’s material carbon footprint and depreciation carbon footprint are much higher than those of Japan, whereas the purchased electricity and heat carbon footprint in China is half that of Japan. China and Japan have similar direct energy consumption carbon footprints. However, CO2 emissions from MSW treatment processes in China (46.46 million tons) is significantly higher than that in Japan (2.72 million tons). The corresponding effects of waste recycling on CO2 emission reductions are considerable, up to 181.37 million tons for China and 96.76 million tons for Japan. Besides, measures were further proposed for optimizing waste management systems in the two countries. In addition, it is argued that the advanced experience that developed countries have in waste management issues can provide scientific support for waste treatment in developing countries such as China.

关键词： waste management     waste recycling     carbon footprint     hybrid LCA    

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标题 作者 时间 类型 操作

废弃沥青材料的循环利用关键技术研究

杨林江

期刊论文

Green Road Construction Technologies in Guangzhou

Guan-feng An,Wen-yuan Huang,Jing-feng Zhang

期刊论文

Copper fractal growth during recycling from waste printed circuit boards by slurry electrolysis

期刊论文

Aging properties and aging mechanism of activated waste rubber powder modified asphalt binder based on

期刊论文

Recycling Materials from Waste Electrical and Electronic Equipment

Jinhui Li

期刊论文

Multi-Component Resource Recycling from Waste Light-Emitting Diode Under Hydrothermal Condition: Plastic

Yongliang Zhang,Lu Zhan,Zhenming Xu,

期刊论文

Region-gridding recycling of bulk organic waste: Emerging views based on coordinated urban and rural

Wenbing Tan, Dongyu Cui, Xiaohui Zhang, Beidou Xi

期刊论文

A critical review on the recycling of copper and precious metals from waste printed circuit boards using

Zebing Wu, Wenyi Yuan, Jinhui Li, Xiaoyan Wang, Lili Liu, Jingwei Wang

期刊论文

risks of heavy metals, polybrominated diphenyl ethers, and polychlorinated dibenzo-dioxins/furans at e-wasterecycling sites in South China

期刊论文

Characterization of chlorine and heavy metals for the potential recycling of bottom ash from municipalsolid waste incinerators as cement additives

Boran WU, Dongyang WANG, Xiaoli CHAI, Fumitake TAKAHASHI, Takayuki SHIMAOKA

期刊论文

Spent rechargeable lithium batteries in e-waste: composition and its implications

Xianlai ZENG,Jinhui LI

期刊论文

Thermal cracking of waste printed wiring boards for mechanical recycling by using residual steam preprocessing

Yao CHEN, Jinhui LI, Huabo DUAN, Zhishi WANG

期刊论文

Recycling polymeric waste from electronic and automotive sectors into value added products

Abhishek Kumar, Veena Choudhary, Rita Khanna, Romina Cayumil, Muhammad Ikram-ul-Haq, Veena Sahajwalla, Shiva Kumar I. Angadi, Ganapathy E. Paruthy, Partha S. Mukherjee, Miles Park

期刊论文

Toward separation at source: Evolution of Municipal Solid Waste management in China

Jianguo Liu, Shuyao Yu, Yixuan Shang

期刊论文

Carbon footprint assessment for the waste management sector: A comparative analysis of China and Japan

Lu SUN, Zhaoling LI, Minoru FUJII, Yasuaki HIJIOKA, Tsuyoshi FUJITA

期刊论文